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Teaching at the
University of Cologne

Lecture

Advanced
Organic
Chemistry

SoSe & WiSe 
Wed, 10:00 or 11:00
Org.Chem.
HS-III    or
ZOOM-lectures

Exams
where&when

Advanced Organic Chemistry
Reaction Mechanisms & Pericyclic Reactions - Basic Principles & Synthetic Applications

lecture:
 1) Hammett

2) Catalysis
3) Pericyclics
special topics: Hammett-correlations catalyses
aromaticity MO-theory
Nobel prizes: Organo-Ecat_NP21 QM-MM_NP13
Pd-CrossCoupl_NP10 Metathesis_NP05
TM-Ecat_NP01 CompChem_NP98



computational illustrations (PBE/DZVP-D3BJ)
pericyclic-additions Diels-Alder  s-cis-MD  1CH2 + ethene cyclopropanation
Schenck-ene CH-insert.  
electrocyclics: cyclopropyl-cation   cyclopropyl-anion  
cyclobutene   cyclohexadiene  
vinylcyclopropane  
sigmatropics: heptatriene  WM-prot-cyhexdienone  
Vogel-Aromat   walk-5,   walk-6-cationic,   walk-6-anionic
       excited: triplet-cyclobutene   triplet-cyclohexadiene   


literature  
tunneling_PRS_CSI19_802, tunneling_PRS_Trends20,  isolongifolene_NatCat18_609,          
Diels_Alder_1928,  Alder_NobelLecture_1950,  Dewar_TS_aromat_1971,
KNH_pericycl_TS_1995, PVRS_aromat_TS_2014, KIE_AsymReactions_2010,  
Huisgen-[3+2]-CyAdd.,                     
  
exams 
oca_SS18_1,  oca_SS18_2,  oca_SS18_3,          oca_WS18_1,  oca_WS18_2,  oca_WS18_3  
oca_SS19_1,  oca_SS19_2,  oca_SS19_3,          oca_WS19_1,  oca_WS19_2,  oca_WS19_3        
oca_SS20_1,  oca_SS20_2,  oca_SS20_3,          oca_WS20_1,  oca_WS20_2,  oca_WS20_3    
oca_SS21_1,  oca_SS21_2,  oca_SS21_3,          oca_WS21_1,  oca_WS21_2,  oca_WS21_3
oca_SS22_1,  oca_SS22_2,  oca_SS22_3,          oca_WS22_1,  oca_WS22_2,  oca_WS22_3
oca_SS23_1,  oca_SS23_2,  oca_SS23_3,          oca_WS23_1,  oca_WS23_2,  oca_WS23_3
oca_SS24_1,  oca_SS24_2,  oca_SS24_3,          oca_WS24_1,  oca_WS24_2,  oca_WS24_3
oca_SS25_1,  oca_SS25_2,  oca_SS25_3,          oca_WS25_1,  oca_WS25_2,  oca_WS25_3